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Author(s):   Taketani, F.; Nakayama, T.; Takahashi, K.; Matsumi, Y.; Hurley, M.D.; Wallington, T.J.; Toft, A.; Andersen, M.PS.
Title:   Atmospheric chemistry of CH3CHF2 (HFC-152a): Kinetics, mechanisms, and products of Cl atom- and OH radical-initiated oxidation in the presence and absence of NOx
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   9061 - 9069
Year:   2005
Reference type:   Journal article
Squib:   2005TAK/NAK9061-9069

Reaction:   CH3CHF2 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH3Cl + ·Cl → Products
Reference reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   4.9x10-1±1.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Cl-atoms generated by the uv photolysis of Cl2.

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