Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Kern, R.D.; Singh, H.J.; Wu, C.H.
Title:   Thermal decomposition of 1,2 butadiene
Journal:   Int. J. Chem. Kinet.
Volume:   20
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988KER/SIN731

Reaction:   1,2-butadiene·CH3 + CH2=C=CH
Reaction order:   1
Temperature:   1300 - 2000 K
Pressure:  0.20 - 0.56 bar
Rate expression:   1.0x1012 [s-1] e-248603 [J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 1.03E2
1350 2.41E2
1400 5.31E2
1450 1.11E3
1500 2.20E3
1550 4.19E3
1600 7.66E3
1650 1.35E4
1700 2.30E4
1750 3.80E4
1800 6.11E4
1850 9.57E4
1900 1.46E5
1950 2.19E5
2000 3.22E5