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Author(s):   Kern, R.D.; Singh, H.J.; Wu, C.H.
Title:   Thermal decomposition of 1,2 butadiene
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988KER/SIN731

Reaction:   1,2-butadiene·CH3 + CH2=C=CH
Reaction order:   1
Temperature:   1300 - 2000 K
Pressure:  0.20 - 0.56 bar
Rate expression:   1.0x1012 [s-1] e-248603 [J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 1.03E2
1350 2.41E2
1400 5.31E2
1450 1.11E3
1500 2.20E3
1550 4.19E3
1600 7.66E3
1650 1.35E4
1700 2.30E4
1750 3.80E4
1800 6.11E4
1850 9.57E4
1900 1.46E5
1950 2.19E5
2000 3.22E5