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Author(s):   Hidaka, Y.; Higashihara, T.; Ninomiya, N.; Oshita, H.; Kawano, H.
Title:   Thermal isomerization and decomposition of 2-butyne in shock waves
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   10977 - 10983
Year:   1993
Reference type:   Journal article
Squib:   1993HID/HIG10977-10983

Reaction:   1,2-butadiene·CH3 + CH2=C=CH
Reaction order:   1
Temperature:   1100 - 1600 K
Rate expression:   2.0x1015 [s-1] e-313456 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 2.61E0
1150 1.16E1
1200 4.54E1
1250 1.59E2
1300 5.09E2
1350 1.49E3
1400 4.04E3
1450 1.02E4
1500 2.43E4
1550 5.47E4
1600 1.17E5