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Title: Thermal isomerization and decomposition of 2-butyne in shock waves
Journal: J. Phys. Chem.
Volume: 97
Page(s): 10977 - 10983
Year: 1993
Reference type: Journal article
Squib: 1993HID/HIG10977-10983
Reaction:
1,2-butadiene → ·CH3 + CH2=C=CH
Reaction order:
1
Temperature:
1100 - 1600
K
Rate expression:
2.0x1015 [s-1] e-313456 [J/mole]/RT
Bath gas:
Ar
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1100 | 2.61E0 |
| 1150 | 1.16E1 |
| 1200 | 4.54E1 |
| 1250 | 1.59E2 |
| 1300 | 5.09E2 |
| 1350 | 1.49E3 |
| 1400 | 4.04E3 |
| 1450 | 1.02E4 |
| 1500 | 2.43E4 |
| 1550 | 5.47E4 |
| 1600 | 1.17E5 |