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Author(s):   Wallington, T.J.; Hurley, M.D.; Shi, J.; Maricq, M.M.; Sehested, J.; Nielsen, O.J.; Ellermann, T.
Title:   A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   651 - 665
Year:   1993
Reference type:   Journal article
Squib:   1993WAL/HUR651-665

Reaction:   CHF3 + ·F·CF3 + HF
Reaction order:   2
Reference reaction:   CH4 + ·F·CH3 + HF
Reference reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   2.0x10-3±3.0x10-4
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

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