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Author(s):   Strausz, O.P.; O'Callaghan, W.B.; Lown, E.M.; Gunning, H.E.
Title:   Reactions of Sulfur Atoms. XII. Arrhenius Parameters for the Addition to Olefins and Acetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971STR/OCA559

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971STR/OCA559   C2H4 + SThiirane  298   1.33E-12           1.33E-12  2
  1971STR/OCA559   C2H2 + S → Thiirene  298 - 450   6.19       8398   0.21  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   CH3CCH + SThiirene, methyl-  298 - 450   6.19       3766   1.35  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   CH2=CHCl + S → Adduct  298 - 450   3.40       2178   1.41  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   CH2=CHF + S → Adduct  298 - 450   1.40       3051   0.41  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   1-C4H8 + S → Thiirane, ethyl-  298 - 450   0.75       -7200   13.71  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   1,3-Butadiene + SThiirane, ethenyl-  298 - 450   2.40       -8564   76.08  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   CH3CH=CH2 + SMethylthiirane  298 - 450   1.00       -4773   6.86  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   Isobutene + SThiirane, 2,2-dimethyl-  298 - 450   0.97       -9894   52.66  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   C2F4 + S → Thiirane, tetrafluoro-  298 - 450   1.40       5862   0.13  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   Cyclopentene + S → 6-Thiabicyclo[3.1.0]hexane  298 - 450   0.67       -8980   25.12  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   Thiirane + SC2H4 + S2  298 - 450   8.30       -7533   174  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   2-butyne + SThiirene, dimethyl-  298 - 450   2.70       -5438   24.24  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   (CH3)2C=CHCH3 + SThiirane, trimethyl-  298 - 450   0.51       -1.26E04   83.87  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   C2H5C(CH3)=CH2 + S → Thiirane, 2-ethyl-2-methyl-  298 - 450   0.78       -1.18E04   91.53  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   (CH3)2C=C(CH3)2 + SThiirane, tetramethyl-  298 - 450   0.50       -1.41E04   145  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   (Z)-2-C4H8 + SThiirane, 2,3-dimethyl-, cis-  298 - 450   0.53       -8730   17.97  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   (E)-2-C4H8 + SThiirane, 2,3-dimethyl-, trans  298 - 450   0.65       -8398   19.27  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   C2D4 + S → Thiirane-d4  298 - 450   1.14           1.14  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   Methylthiirane + SCH3CH=CH2 + S2  298 - 450   8.39       -8813   294  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   CH3CF=CH2 + S → Adduct  298 - 450   1.20       6277   0.10  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   (Z)-CHF=CHF + S → Adduct  298 - 450   1.70       1.13E04   0.02  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   (E)-CHF=CHF + S → Adduct  298 - 450   3.40       1.10E04   0.04  2
  Reference reaction:  C2H4 + S → Products 2
  1971STR/OCA559   (Z)-CHD=CHD + S → Thiirane-2,3-d2, cis-  298 - 450   1.04           1.04  2
  Reference reaction:  C2H4 + SThiirane 2
  1971STR/OCA559   CH2=CD2 + S → Adduct  298 - 450   1.07           1.07  2
  Reference reaction:  C2H4 + SThiirane 2

Search returned 25 records.