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Author(s):   Hoyermann, K.; Maarfeld, S.; Nacke, F.; Nothdurft, J.; Olzmann, M.; Wehmeyer, J.; Welz, O.; Zeuch, T.
Title:   Rate coefficients for cycloalkyl plus O reactions and product branching in the decomposition of chemically activated cycloalkoxy radicals: an experimental and theoretical study
Journal:   Phys. Chem. Chem. Phys.
Volume:   12
Page(s):   8954 - 8968
Year:   2010
Reference type:   Journal article
Squib:   2010HOY/MAA8954-8968

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2010HOY/MAA8954-8968   Cyclohexyl + → Products  250 - 558   2.21E-10   0.11       2.21E-10  2
  2010HOY/MAA8954-8968   Cyclooctyl radical + → Products  268 - 363   2.59E-10   0.66       2.59E-10  2
  2010HOY/MAA8954-8968   Cycloheptyl + → Products  298   3.07E-10           3.07E-10  2
  2010HOY/MAA8954-8968   Cyclohexyl + Cyclohexanone +   298   0.24           0.24  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + → CH2=CHCH2CH2CH2CHO +   298   0.30           0.30  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + → ·CH2CH2CH2CHO + C2H4  298   0.28           0.28  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + ·C2H5 + CH2=CHCH2CHO  298   0.30           0.30  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + 1-C5H10 + HCO  298   0.04           0.04  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + CH2=CHCHO + 1-C3H7  298   0.14           0.14  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + Cyclooctanone +   298   0.23           0.23  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + + CH2=CHCH2CH2CH2CH2CH2CHO  298   <0.19           0.19  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + C2H4 + ·CH2(CH2)4CHO  298   0.68           0.68  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + → CH2=CHCH2CH2CH2CHO + ·C2H5  298   <0.19           0.19  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + 1-C5H10 + ·CH2CH2CHO  298   <0.19           0.19  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + CH2=CHCH2CH2CHO + 1-C3H7  298   <0.19           0.19  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + CH2=CHCH2CH2CHO + 1-C3H7  298   0.01           0.01  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + 1-C6H12 + CH2=CHO·  298   0.06           0.06  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + 1-C5H10 + ·CH2CH2CHO  298   0.01           0.01  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + → CH2=CHCH2CH2CH2CHO + ·C2H5  298   0.02           0.02  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + C2H4 + ·CH2(CH2)4CHO  298   0.80           0.80  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + + CH2=CHCH2CH2CH2CH2CH2CHO  298   0.04           0.04  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclooctyl radical + Cyclooctanone +   298   0.05           0.05  2
  Reference reaction:  Cyclooctyl radical + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + Cyclohexanone +   298   0.05           0.05  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + → CH2=CHCH2CH2CH2CHO +   298   0.03           0.03  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + → ·CH2CH2CH2CHO + C2H4  298   0.80           0.80  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + ·C2H5 + CH2=CHCH2CHO  298   0.01           0.01  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + 1-C5H10 + HCO  298   0.02           0.02  2
  Reference reaction:  Cyclohexyl + → Products 2
  2010HOY/MAA8954-8968   Cyclohexyl + CH2=CHCHO + 1-C3H7  298   0.09           0.09  2
  Reference reaction:  Cyclohexyl + → Products 2

Search returned 28 records.