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Title: The kinetics and the mechanism of the thermal decomposition of bis(trifluoromethyl) trioxide. The influence of carbonmonoxide on its decomposition
Journal: Int. J. Chem. Kinet.
Volume: 13
Page(s):
Year: 1981
Reference type: Journal article
Squib: 1981CZA/SCH639
Reaction:
CF3O-O-OCF3 → CF3O2 + CF3O
Reaction order:
1
Temperature:
315 - 343
K
Pressure: 6.57E-2 - 0.67 bar
Rate expression:
5.48x1015 [±2.7x1014 s-1] e-127211 [±1272 J/mole]/RT
Bath gas:
CO
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 315 | 4.41E-6 |
| 325 | 1.97E-5 |
| 343 | 2.33E-4 |