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Accessibility information
Author(s):   Jayne, J.T.; Davidovits, P.
Title:   Sodium atom reactions with the bromochloromethanes: Branching ratios and relative reaction rates
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   3574 - 3579
Year:   1989
Reference type:   Journal article
Squib:   1989JAY/DAV3574-3579

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1989JAY/DAV3574-3579   CHCl3 + Na → Products  340   0.12              2
  Reference reaction:  CCl4 + Na·CCl3 + NaCl 2
  1989JAY/DAV3574-3579   CH3Br + Na → Products  340   0.02              2
  Reference reaction:  CCl4 + Na·CCl3 + NaCl 2
  1989JAY/DAV3574-3579   CH2ClBr + Na → Products  340   0.30              2
  Reference reaction:  CCl4 + Na·CCl3 + NaCl 2
  1989JAY/DAV3574-3579   CH2ClBr + Na·CH2Cl + NaBr  340   4.00              2
  Reference reaction:  CH2ClBr + NaNaCl + ·CH2Br 2
  1989JAY/DAV3574-3579   CHBrCl2 + Na → Products  340   0.27              2
  Reference reaction:  CCl4 + Na·CCl3 + NaCl 2
  1989JAY/DAV3574-3579   CHBrCl2 + NaCHCl2 + NaBr  340   1.83              2
  Reference reaction:  CHBrCl2 + NaNaCl + ·CHBrCl 2
  1989JAY/DAV3574-3579   CCl3Br + Na → Products  340   0.60              2
  Reference reaction:  CCl4 + Na·CCl3 + NaCl 2
  1989JAY/DAV3574-3579   CCl3Br + Na·CCl3 + NaBr  340   0.55              2
  Reference reaction:  CCl3Br + NaNaCl + BrCCl2 2

Search returned 8 records.