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Author(s):
Alwe, H. D.; Walavalkar, M. P.; Sharma, A.; Dhanya, S.; Naik, P. D.
Title:
Tropospheric oxidation of cyclic unsaturated ethers in the day-time: Comparison of the reactions with Cl, OH and O3 based on the determination of their rate coefficients at 298 K
Journal:
Atmos. Environ.
Volume:
82
Page(s):
113 - 120
Year:
2014
Reference type:
Journal article
Squib:
2014ALW/WAL113-120
Reaction:
2,3-Dihydrofuran + ·OH → Products
Reaction order:
2
Reference reaction:
(E)-2-C4H8 + ·OH → Products
Temperature:
298
K
Pressure: 1.07 bar
Rate expression:
1.2x10-10 [±2.79x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
The error quoted is a combination of the 2σ error of the rate constant ratio and the reported error of the rate constant of the reference reaction, both combined using the statistical error propagation equation.
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