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Title: Tropospheric oxidation of cyclic unsaturated ethers in the day-time: Comparison of the reactions with Cl, OH and O3 based on the determination of their rate coefficients at 298 K
Journal: Atmos. Environ.
Volume: 82
Page(s): 113 - 120
Year: 2014
Reference type: Journal article
Squib: 2014ALW/WAL113-120
Reaction:
3,4-Dihydro-2H-pyran + ·Cl → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.07 bar
Rate expression:
6.15x10-10 [±8.4x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Average of the values obtained using 1-butene and n-hexane as reference compounds.
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