Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Tonokura, K.; Norikane, Y.; Koshi, M.; Nakano, Y.; Nakamichi, S.; Goto, M.; Hashimoto, S.; Kawasaki, M.; Anderson, M.P.S.; Hurley, M.D.; Wallington, T.J.
Title:   Cavity Ring-down Study of the Visible Absorption Spectrum of the Phenyl Radical and Kinetics of Its Reactions with Cl, Br, Cl2, and O2
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   5908 - 5917
Year:   2002
Reference type:   Journal article
Squib:   2002TON/NOR5908-5917

Reaction:   Phenyl + ·ClChlorobenzene
Reaction order:   2
Temperature:   298 K
Rate expression:   1.2x10-10 [±8.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Pulsed laser photolysis of phenyl chloride / cavity ring-down laser absorption spectroscopy of phenyl, slow flow reactor, quantitative visible absorption spectrum of phenyl radical, uncertainties are statistical 2 sigma, also some low level B3LYP DFT theory to support spectroscopy

View full bibliographic record.