Author(s):   Wu, F.; Carr, R.W.
Title:   The chloromethoxy radical: kinetics of the reaction with O₂ and the unimolecular elimination of HCl at 306 K
Journal:   Chem. Phys. Lett.
Volume:   305
Page(s):   44 - 50
Year:   1999
Reference type:   Journal article
Squib:   1999WU/CAR44-50

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1999WU/CAR44-50	CH₂ClO → HCO + HCl	306	4000		1
1999WU/CAR44-50	CH₂ClO → HCO + HCl	306	600		1
1999WU/CAR44-50	HO₂ + CH₂ClO₂ → O₂ + CH₂ClOOH	306	0.50		2
Reference reaction: HO₂ + CH₂ClO₂ → Products				2
1999WU/CAR44-50	O₂ + CH₂ClO → HC(O)Cl + HO₂	306	2.81E-13		2
1999WU/CAR44-50	O₂ + CH₂ClO → HC(O)Cl + HO₂	306	5.00E-18		2
Reference reaction: CH₂ClO → HCO + HCl				1
1999WU/CAR44-50	O₂ + CH₂ClO → HC(O)Cl + HO₂	306	5.20E-16		2
Reference reaction: CH₂ClO → HCO + HCl				1

Search returned 6 records.