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Title: Free radical addition to olefins. Part 6.-Addition of sulphur chloride pentafluoride to fluoro-olefins
Journal: Trans. Faraday Soc.
Volume: 66
Page(s):
Year: 1970
Reference type: Journal article
Squib: 1970SID/TED2038
Reaction:
SF5CHFCF2· → C2HF3 + SF5
Reaction order:
1
Reference reaction:
SF5CHFCF2· + SF5Cl → SF5 + SF5CHFCF2Cl
Reference reaction order:
2
Temperature:
313 - 418
K
Rate expression:
1.9x1036 [molecule/cm3] e-35170 [±4215 J/mole]/RT
Uncertainty:
2.0
Bath gas:
SF5Cl
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [molecule/cm3] |
|---|---|
| 313 | 2.57E30 |
| 325 | 4.24E30 |
| 350 | 1.07E31 |
| 375 | 2.40E31 |
| 400 | 4.86E31 |
| 418 | 7.67E31 |