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Author(s):   Sidebottom, H.W.; Tedder, J.M.; Walton, J.C.
Title:   Free radical addition to olefins. Part 6.-Addition of sulphur chloride pentafluoride to fluoro-olefins
Journal:   Trans. Faraday Soc.
Volume:   66
Year:   1970
Reference type:   Journal article
Squib:   1970SID/TED2038

Reaction:   SF5CHFCF2· → C2HF3 + SF5
Reaction order:   1
Reference reaction:   SF5CHFCF2· + SF5ClSF5 + SF5CHFCF2Cl
Reference reaction order:   2
Temperature:   313 - 418 K
Rate expression:   1.9x1036 [molecule/cm3] e-35170 [±4215 J/mole]/RT
Uncertainty:   2.0
Bath gas:   SF5Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
313 2.57E30
325 4.24E30
350 1.07E31
375 2.40E31
400 4.86E31
418 7.67E31