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Title: Kinetic isotope effects and rate constants for the gas-phase reactions of three deuterated toluenes with OH from 298 to 353 K
Journal: Int. J. Chem. Kinet.
Volume: 44
Page(s): 821 - 827
Year: 2012
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2012KIM/STE821-827
Reaction:
Toluene + ·OH → Products
Reaction order:
2
Reference reaction:
C6D5CD3 + ·OH → Products
Reference reaction order:
2
Temperature:
298 - 353
K
Pressure: 1.01 bar
Rate expression:
1.28 e-532 [±732 J/mole]/RT
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
The errors represent standard errors. The uncertainty in the preexponential factor is expressed as follows: A = (1.28 (+0.40 / -0.31).
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 298 | 1.03E0 |
| 300 | 1.03E0 |
| 325 | 1.05E0 |
| 350 | 1.07E0 |
| 353 | 1.07E0 |