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Author(s):   Boone, G.D.; Agyin, F.; Robichaud, D.J.; Tao, F.-M.; Hewitt, S.A.
Title:   Rate Constants for the Reactions of Chlorine Atoms with Deuterated Methanes: Experiment and Theory
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   1456 - 1464
Year:   2001
Reference type:   Journal article
Squib:   2001BOO/AGY1456-1464

Reaction:   CH2D2 + ·Cl → Products
Reaction order:   2
Reference reaction:   (13)CO + ·Cl → (13)CO
Reference reaction order:   3
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   3.4x10-14 [±5.0x10-15 molecule/cm3]
Bath gas:   air
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Reaction rates were measured in synthetic air relative to Cl + 13CO + M -> Cl13CO + M, where kref (Cl+CH4) = 3.2 x 10-14 cm3 molecule s-1 is used to derive k.

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