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Author(s):   Smith, I.W.M.; Wrigley, D.J.
Title:   Time resolved vibrational chemiluminescence: Rate constants for the reactions F + HBr, HI →’ HF + Br, I and for the relaxation of HF(μ=6) by HBr, HI, CO2, N2O, CO, N2 and O2
Journal:   Chem. Phys.
Volume:   63
Year:   1981
Reference type:   Journal article
Squib:   1981SMI/WRI321

Reaction:   HBr + ·FHF + Br·
Reaction order:   2
Temperature:   295 K
Pressure:  6.27E-2 - 0.13 bar
Rate expression:   6.19x10-11 [±4.98x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Chemiluminescence

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