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Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Isomerization and decomposition of propylene oxide. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   1161 - 1170
Year:   1994
Reference type:   Journal article
Squib:   1994LIF/TAM1161-1170

Reaction:   MethyloxiraneAcetone
Reaction order:   1
Temperature:   835 - 1160 K
Pressure:  2.03 bar
Rate expression:   1.0x1014 [s-1] e-250266 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
835 2.21E-2
850 4.18E-2
875 1.15E-1
900 2.99E-1
925 7.38E-1
950 1.74E0
975 3.91E0
1000 8.47E0
1025 1.76E1
1050 3.55E1
1075 6.91E1
1100 1.31E2
1125 2.40E2
1150 4.29E2
1160 5.38E2