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Title: Isomerization and decomposition of propylene oxide. Studies with a single-pulse shock tube
Journal: J. Phys. Chem.
Volume: 98
Page(s): 1161 - 1170
Year: 1994
Reference type: Journal article
Squib: 1994LIF/TAM1161-1170
Reaction:
Methyloxirane → Acetone
Reaction order:
1
Temperature:
835 - 1160
K
Pressure: 2.03 bar
Rate expression:
1.0x1014 [s-1] e-250266 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 835 | 2.21E-2 |
| 850 | 4.18E-2 |
| 875 | 1.15E-1 |
| 900 | 2.99E-1 |
| 925 | 7.38E-1 |
| 950 | 1.74E0 |
| 975 | 3.91E0 |
| 1000 | 8.47E0 |
| 1025 | 1.76E1 |
| 1050 | 3.55E1 |
| 1075 | 6.91E1 |
| 1100 | 1.31E2 |
| 1125 | 2.40E2 |
| 1150 | 4.29E2 |
| 1160 | 5.38E2 |