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Accessibility information
Author(s):   Westberg, K.; Greene, E.F.
Title:   Dissociation of HBr and Br2 in shock waves
Journal:   J. Chem. Phys.
Volume:   56
Page(s):   2713 - 2722
Year:   1972
Reference type:   Journal article
Squib:   1972WES/GRE2713-2722

Reaction:   HBrBr· +
Reaction order:   2
Temperature:   1500 - 2700 K
Rate expression:   2.24x10-7 [cm3/molecule s] (T/298 K)-2.00 e-368331 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV emission

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1500 1.32E-21
1600 7.35E-21
1700 3.32E-20
1800 1.26E-19
1900 4.13E-19
2000 1.19E-18
2100 3.11E-18
2200 7.40E-18
2300 1.62E-17
2400 3.33E-17
2500 6.42E-17
2600 1.17E-16
2700 2.04E-16