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 Author(s):   Orlando, J.J.; Tyndall, G.S.; Apel, E.C.; Riemer, D.D.; Paulson, S.E.
Title:   Rate Coefficients and Mechanisms of the Reaction of Cl-Atoms with a Series of Unsaturated Hydrocarbons Under Atmospheric Conditions
Journal:   Int. J
Volume:   35
Page(s):   334 - 353
Year:   2003
Reference type:   Journal article
Squib:   2003ORL/TYN334-353

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003ORL/TYN334-353   CH2=C(CH3)CH=CH2 + ·Cl → Products  298   2.99           2.99  2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2003ORL/TYN334-353   CH2=CHCOCH3 + ·Cl → Products  298   1.50           1.50  2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2003ORL/TYN334-353   CH2=CHCOCH3 + ·Cl → Products  298   0.81           0.81  2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2003ORL/TYN334-353   Methacrolein + ·Cl → Products  298   1.77           1.77  2
  Reference reaction:  C3H8 + ·Cl → Products 2
  2003ORL/TYN334-353   Methacrolein + ·Cl → Products  298   0.82           0.82  2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2003ORL/TYN334-353   (E)-2-C4H8 + ·Cl → Products  298   1.54           1.54  2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2003ORL/TYN334-353   1-C4H8 + ·Cl → Products  298   1.12           1.12  2
  Reference reaction:  CH3CH=CH2 + ·Cl → Products 2
  2003ORL/TYN334-353   1-C4H8 + ·Cl → Products  298   3.17           3.17  2
  Reference reaction:  C2H4 + ·Cl → Products 2
  2003ORL/TYN334-353   CH2=C(CH3)CH=CH2 + ·Cl → Products  298   4.30E-10           4.30E-10  2
  2003ORL/TYN334-353   CH2=CHCOCH3 + ·Cl → Products  298   2.15E-10           2.15E-10  2
  2003ORL/TYN334-353   CH2=CHCOCH3 + ·Cl → Products  298   2.27E-10           2.27E-10  2
  2003ORL/TYN334-353   CH2=CHCOCH3 + ·Cl → Products  298   2.20E-10           2.20E-10  2
  2003ORL/TYN334-353   Methacrolein + ·Cl → Products  298   2.53E-10           2.53E-10  2
  2003ORL/TYN334-353   Methacrolein + ·Cl → Products  298   2.16E-10           2.16E-10  2
  2003ORL/TYN334-353   Methacrolein + ·Cl → Products  298   2.35E-10           2.35E-10  2
  2003ORL/TYN334-353   (E)-2-C4H8 + ·Cl → Products  298   4.00E-10           4.00E-10  2
  2003ORL/TYN334-353   1-C4H8 + ·Cl → Products  298   2.90E-10           2.90E-10  2
  2003ORL/TYN334-353   1-C4H8 + ·Cl → Products  298   3.10E-10           3.10E-10  2
  2003ORL/TYN334-353   1-C4H8 + ·Cl → Products  298   3.00E-10           3.00E-10  2
Search returned 19 records.