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Author(s):   Tschuikow-Roux, E.; Niedzielski, J.
Title:   Secondary kinetic isotope effects in hydrogen and deuterium abstraction by chlorine atoms from the chloromethyl group in gaseous ethyl chlorides: effects of isotopic substitution in the adjacent methyl group
Journal:   J. Photochem.
Volume:   27
Page(s):   141 - 150
Year:   1984
Reference type:   Journal article
Squib:   1984TSC/NIE141-150

Reaction:   CD3CH2Cl + ·Cl → Other Products + HCl
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   282 - 368 K
Pressure:  2.67E-2 bar
Rate expression:   1.24±3.7x10-2 e9478 [±95.62 J/mole]/RT
Bath gas:   CD3CH2Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
282 7.06E1
300 5.54E1
325 4.14E1
350 3.22E1
368 2.75E1