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Title: The reactions of active nitrogen with the butanes
Journal: Can. J. Chem.
Volume: 32
Page(s):
Year: 1954
Reference type: Journal article
Squib: 1954BAC/WIN718
Reaction:
iso-C4H10 + N → Other Products + HCN
Reaction order:
2
Temperature:
373 - 533
K
Pressure: 1.79E-3 bar
Rate expression:
2.69x10-14 [cm3/molecule s] e-13054 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 373 | 4.00E-16 |
| 375 | 4.09E-16 |
| 400 | 5.31E-16 |
| 425 | 6.69E-16 |
| 450 | 8.21E-16 |
| 475 | 9.87E-16 |
| 500 | 1.16E-15 |
| 525 | 1.35E-15 |
| 533 | 1.41E-15 |