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Author(s):   Lee, J.; Caster, K.; Maddaleno, T.; Donnellan, Z.; Selby, T.M.; Goulay, F.
Title:   Kinetic study of the CN radical reaction with 2-methylfuran
Journal:   Int. J. Chem. Kinet.
Volume:   52
Page(s):   838 - 851
Year:   2020
Reference type:   Journal article
Squib:   2020LEE/CAS838-851

Reaction:   CN + 2-Methylfuran → Products
Reaction order:   2
Temperature:   304 - 440 K
Pressure:  2.93E-3 - 1.01E-2 bar
Rate expression:   2.8x10-10 [±1.8x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   There is good agreement of the rate constants within the error (2σ) over the experimental temperature range, suggesting no temperature dependence within that experimental range.

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