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Author(s):   Stutz, J.; Ezell, M.J.; Finlayson-Pitts, B.J.
Title:   Inverse kinetic isotope effect in the reaction of atomic chlorine with C2H4 and C2D4
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   9187 - 9190
Year:   1997
Reference type:   Journal article
Squib:   1997STU/EZE9187-9190

Reaction:   C2D4 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Temperature:   295 K
Pressure:  1.33E-3 bar
Rate expression:   7.8x10-13 [±1.64x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

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