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 Author(s):   Huang, H. F.; Merthe, D. J.; Zador, J.; Jusinski, L. E.; Taatjes, C. A.
Title:   New experiments and validated master-equation modeling for OH production in propyl + O2 reactions
Journal:   Proc. Combust. Inst.
Volume:   33
Page(s):   293 - 299
Year:   2011
Reference type:   Journal article
Squib:   2011HUA/MER293-299

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2011HUA/MER293-299   Propyl Radical + O2 → Other Products + ·OH  400 - 700                  2
  Reference reaction:  Propyl Radical + O2 → Products 2
  2011HUA/MER293-299   1-C3H7 + O2 → CH3CH2CH2OO·  300 - 750   1.63E-10   -3.28   8306      2
  2011HUA/MER293-299   1-C3H7 + O2 → CH3CH(·)CH2OOH  300 - 750   2.05E-13   -4.68   2.09E04      2
  2011HUA/MER293-299   1-C3H7 + O2 → (·)CH2CH2CH2OOH  300 - 750   6.61E-20   10.01   -3.08E04      2
  2011HUA/MER293-299   1-C3H7 + O2 → CH3CH=CH2 + HO2  300 - 750   3.03E-08   -5.12   5.26E04      2
  2011HUA/MER293-299   1-C3H7 + O2 → Methyloxirane + ·OH  300 - 750   2.34E-08   -6.08   5.71E04      2
  2011HUA/MER293-299   2-C3H7 + O2 → (CH3)2CHO2  300 - 750   1.95E-08   -5.76   1.69E04      2
  2011HUA/MER293-299   2-C3H7 + O2 → ·CH2CH(OOH)CH3  300 - 750   5.31E-09   -4.31   3.57E04      2
  2011HUA/MER293-299   2-C3H7 + O2 → Methyloxirane + ·OH  300 - 750   3.51E-07   -7.99   6.14E04      2
  2011HUA/MER293-299   (CH3)2CHO2 → 2-C3H7 + O2  300 - 750   6.72E19   -8.61   1.62E05      1
  2011HUA/MER293-299   (CH3)2CHO2 → ·CH2CH(OOH)CH3  300 - 750   7.96E09   -0.04   1.08E05      1
  2011HUA/MER293-299   (CH3)2CHO2 → CH3CH=CH2 + HO2  300 - 750   3.35E18   -9.20   1.59E05      1
  2011HUA/MER293-299   (CH3)2CHO2 → Methyloxirane + ·OH  300 - 750   6.16E26   -22.97   2.26E05      1
  2011HUA/MER293-299   ·CH2CH(OOH)CH3 → 2-C3H7 + O2  300 - 750   1.09E14   -5.45   1.01E05      1
  2011HUA/MER293-299   ·CH2CH(OOH)CH3 → (CH3)2CHO2  300 - 750   1.20E16   -10.37   9.53E04      1
  2011HUA/MER293-299   ·CH2CH(OOH)CH3 → CH3CH=CH2 + HO2  300 - 750   1.62E16   -7.28   9.48E04      1
  2011HUA/MER293-299   ·CH2CH(OOH)CH3 → Methyloxirane + ·OH  300 - 750   2.17E15   -6.01   8.03E04      1
  2011HUA/MER293-299   CH3CH2CH2OO· → 1-C3H7 + O2  300 - 750   7.46E21   -12.51   1.77E05      1
  2011HUA/MER293-299   CH3CH2CH2OO· → CH3CH(·)CH2OOH  300 - 750   2.73E29   -26.69   2.40E05      1
  2011HUA/MER293-299   CH3CH2CH2OO· → (·)CH2CH2CH2OOH  300 - 750   1932   16.29   6.39E04      1
  2011HUA/MER293-299   CH3CH2CH2OO· → CH3CH=CH2 + HO2  300 - 750   6.06E20   -13.03   1.76E05      1
  2011HUA/MER293-299   CH3CH2CH2OO· → Methyloxirane + ·OH  300 - 750   4.08E21   -15.43   1.86E05      1
  2011HUA/MER293-299   CH3CH(·)CH2OOH → 1-C3H7 + O2  300 - 750   7.93E35   -34.69   2.76E05      1
  2011HUA/MER293-299   CH3CH(·)CH2OOH → CH3CH2CH2OO·  300 - 750   8.06E14   -10.04   9.54E04      1
  2011HUA/MER293-299   CH3CH(·)CH2OOH → (·)CH2CH2CH2OOH  300 - 750   4.10E-05   20.36   1.38E04      1
  2011HUA/MER293-299   CH3CH(·)CH2OOH → CH3CH=CH2 + HO2  300 - 750   2.33E14   -6.26   8.48E04      1
  2011HUA/MER293-299   CH3CH(·)CH2OOH → Methyloxirane + ·OH  300 - 750   7.71E14   -5.40   7.24E04      1
  2011HUA/MER293-299   (·)CH2CH2CH2OOH → 1-C3H7 + O2  300 - 750   0.71   19.83   1.16E04      1
  2011HUA/MER293-299   (·)CH2CH2CH2OOH → CH3CH2CH2OO·  300 - 750   8.62E10   -1.56   3.07E04      1
  2011HUA/MER293-299   (·)CH2CH2CH2OOH → CH3CH(·)CH2OOH  300 - 750   2.12E-19   35.26   -1.17E05      1
  2011HUA/MER293-299   (·)CH2CH2CH2OOH → CH3CH=CH2 + HO2  300 - 750   1.93E-05   23.45   -1.45E04      1
  2011HUA/MER293-299   (·)CH2CH2CH2OOH → Methyloxirane + ·OH  300 - 750   1.85E-03   20.17   6128      1
Search returned 32 records.