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Title: A semi-empirical correlation for the rate coefficients for cross- and self-reactions of peroxy radicals in the gas-phase
Journal: Atmos. Environ.
Volume: 39
Page(s): 763 - 771
Year: 2005
Reference type: Journal article
Squib: 2005SHA/RAV763-771
Reaction:
CH3O2· + (CH3)2CHO2 → Products
Reaction order:
2
Temperature:
298
K
Rate expression:
3.5x10-14 [cm3/molecule s]
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
Pressure dependence:
Rate constant is high pressure limit
Comments:
Predicted using a semi-empirical correlation with the thermochemistry of the radicals involved.
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