Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Shallcross, D.E.; Raventos-Duran, M.T.; Bardwell, M.W.; Bacak, A.; Solman, Z.; Percival, C.J.
Title:   A semi-empirical correlation for the rate coefficients for cross- and self-reactions of peroxy radicals in the gas-phase
Journal:   Atmos. Environ.
Volume:   39
Page(s):   763 - 771
Year:   2005
Reference type:   Journal article
Squib:   2005SHA/RAV763-771

Reaction:   CH3O2· + (CH3)2CHO2 → Products
Reaction order:   2
Temperature:   298 K
Rate expression:   3.5x10-14 [cm3/molecule s]
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit
Comments:   Predicted using a semi-empirical correlation with the thermochemistry of the radicals involved.

View full bibliographic record.