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Author(s):   Bouwman, J.; Fournier, M.; Sims, I. R.; Leone, S. R.; Wilson, K. R.
Title:   Reaction Rate and Isomer-Specific Product Branching Ratios of C2H + C4H8: 1-Butene, cis-2-Butene, trans-2-Butene, and Isobutene at 79 K
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   5093 - 5105
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013BOU/FOU5093-5105

Reaction:   1-C4H8 + ·C2H → Products
Reaction order:   2
Temperature:   79.00 K
Pressure:  1.40E11 bar
Rate expression:   1.9x10-10 [±5.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Laval nozzle
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   The error in the reaction rate constant is composed of 3σ in the linear fit together with a contribution of 10% to account for systematic errors.

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