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Accessibility information
Author(s):   Ferguson, K.C.; Whittle, E.
Title:   Kinetics of the vapour-phase bromination of cyclanes and n-butane. C-H bond dissociation energies in cyclanes
Journal:   Trans. Faraday Soc.
Volume:   67
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971FER/WHI2618

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971FER/WHI2618   1-C4H10 + Br· → sec-C4H9 + HBr  319 - 468   8.32E-10       4.46E04      2
  1971FER/WHI2618   1-C4H10 + Br· → sec-C4H9 + HBr  319 - 468   1.41       5097      2
  Reference reaction:  Cyclopentane + Br· → Cyclopentyl + HBr 2
  1971FER/WHI2618   Cyclohexane + Br· → Cyclohexyl + HBr  299 - 511   2.89E-09       4.82E04      2
  1971FER/WHI2618   Cyclohexane + Br· → Cyclohexyl + HBr  299 - 511   3.45       3633      2
  Reference reaction:  1-C4H10 + Br· → sec-C4H9 + HBr 2
  1971FER/WHI2618   Cyclohexane + Br· → Cyclohexyl + HBr  297 - 423   5.11       8980   0.14  2
  Reference reaction:  Cyclopentane + Br· → Cyclopentyl + HBr 2
  1971FER/WHI2618   Cyclohexane + Br· → Cyclohexyl + HBr  328 - 423   6.90       1.50E04      2
  Reference reaction:  Cycloheptane + Br· → Cycloheptyl + HBr 2
  1971FER/WHI2618   Cyclobutane + Br· → Cyclobutyl + HBr  338 - 477   1.20E-09       5.27E04      2
  1971FER/WHI2618   Cyclobutane + Br· → Cyclobutyl + HBr  300 - 469   0.37       3783      2
  Reference reaction:  Cyclohexane + Br· → Cyclohexyl + HBr 2
  1971FER/WHI2618   Cyclobutane + Br· → Cyclobutyl + HBr  338 - 477   2.31       1.38E04      2
  Reference reaction:  Cyclopentane + Br· → Cyclopentyl + HBr 2
  1971FER/WHI2618   Cyclopentane + Br· → Cyclopentyl + HBr  319 - 468   5.89E-10       3.95E04      2
  1971FER/WHI2618   Cyclopentane + Br· → Cyclopentyl + HBr  306 - 473   1.56       6269      2
  Reference reaction:  Cyclohexane + Br· → Cyclohexyl + HBr 2
  1971FER/WHI2618   Cycloheptane + Br· → Cycloheptyl + HBr  328 - 423   3.99E-10       3.33E04      2
Search returned 12 records.