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Accessibility information
Author(s):   Martin, G.
Title:   Gas phase thermolysis of diisopropyl disulfide
Journal:   React. Kinet. Catal. Lett.
Volume:   32
Year:   1986
Reference type:   Journal article
Squib:   1986MAR313

Reaction:   (i-C3H7S)2 → (CH3)2CHS + (CH3)2CHS
Reaction order:   1
Temperature:   547 - 577 K
Pressure:  0.11 - 0.35 bar
Rate expression:   2.19x1014 [s-1] e-192064 [±3841 J/mole]/RT
Uncertainty:   2.4000001
Bath gas:   Cyclohexene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
547 1.00E-4
550 1.26E-4
575 7.82E-4
577 8.99E-4