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Accessibility information
Author(s):   Wang, S.; Parise, T.; Johnson, S.E.; Davidson, D.F.; Hanson, R.K.
Title:   A new diagnostic for hydrocarbon fuels using 3.41-mu m diode laser absorption
Journal:   Combust. Flame
Volume:   186
Page(s):   129 - 139
Year:   2017
Reference type:   Journal article
Squib:   2017WAN/PAR129-139

Reaction:   Methylcyclohexane → Products
Reaction order:   1
Temperature:   1260 - 1400 K
Pressure:  1.52 bar
Rate expression:   3.3x1015 [s-1] e-315950 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   The overall (root-sum-squared) 2σ uncertainty is estimated to be +28%/−34%.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1260 2.63E2
1275 3.76E2
1300 6.66E2
1325 1.16E3
1350 1.97E3
1375 3.28E3
1400 5.38E3