Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kikuchi, M.; Lee, F.S.C.; Rowland, F.S.
Title:   Direct formation of RCl from the gas-phase reaction of thermal atomic chlorine with PbR4 (R = CH3, C2H5)
Journal:   J. Phys. Chem.
Volume:   85
Page(s):   84 - 88
Year:   1981
Reference type:   Journal article
Squib:   1981KIK/LEE84-88

Reaction:   C2H4 + ·Cl → CH2CH2Cl
Reaction order:   2
Reference reaction:   (CH3)4Pb + ·ClCH3Cl + (CH3)3Pb
Reference reaction order:   2
Temperature:   293 K
Pressure:  0.67 - 4.00 bar
Rate expression:   2.0±2.0x10-1
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Unknown
Analytical technique:   Gas chromatography

View full bibliographic record.