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Author(s):   Park, J.; Xu, Z. F.; Xu, K.; Lin, M. C.
Title:   Kinetics for the reactions of phenyl with methanol and ethanol: Comparison of theory and experiment
Journal:   Proc. Combust. Inst.
Volume:   34
Page(s):   473 - 482
Year:   2013
Reference type:   Journal article
Squib:   2013PAR/XU,473-482

Reaction:   CH3OH + Phenyl → Products
Reaction order:   2
Temperature:   304 - 771 K
Pressure:  4.00E-3 - 5.33E-2 bar
Rate expression:   1.3x10-12 [±7.31x10-14 cm3/molecule s] e-7092 [±249 J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   The reaction has been studied using two experimental techniques: pulsed laser photolysis / mass-spectrometry and pulsed laser photolysis / cavity ring-down spectrometry.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
304 7.85E-14
325 9.41E-14
350 1.14E-13
375 1.34E-13
400 1.54E-13
425 1.75E-13
450 1.95E-13
475 2.16E-13
500 2.36E-13
525 2.56E-13
550 2.75E-13
575 2.95E-13
600 3.13E-13
625 3.32E-13
650 3.50E-13
675 3.67E-13
700 3.84E-13
725 4.00E-13
750 4.16E-13
771 4.30E-13