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©NIST, 2013
Accessibility information
Author(s):   Albert, D. R.; Todt, M. A.; Davis, H. F.
Title:   Crossed Molecular Beams Studies of Phenyl Radical Reactions with Propene and trans-2-Butene
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   13967 - 13975
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013ALB/TOD13967-13975

Reaction:   (E)-2-C4H8 + PhenylC6H5-CH=CHCH3 + ·CH3
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Molecular beam
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   No evidence of an H-eliminating channels was observed, indicating that the present channel is exclusive. No thermal rate constants or branching ratios were obtained.

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