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Home ©NIST, 2013 Accessibility information |
Title: Crossed Molecular Beams Studies of Phenyl Radical Reactions with Propene and trans-2-Butene
Journal: J. Phys. Chem. A
Volume: 117
Page(s): 13967 - 13975
Year: 2013
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2013ALB/TOD13967-13975
Reaction:
(E)-2-C4H8 + Phenyl → C6H5-CH=CHCH3 + ·CH3
Reaction order:
2
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Pressure dependence:
None reported
Experimental procedure:
Molecular beam
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
No evidence of an H-eliminating channels was observed, indicating that the present channel is exclusive. No thermal rate constants or branching ratios were obtained.
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