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Author(s):   Banks, J.T.; Scaiano, J.C.; Adam, W.; Oestrich, R.S.
Title:   Thermal and photochemical fragmentation of α,α-dialkoxybenzyl radicals: a comparison of the thermal reactions with laser induced fragmentations by using laser flash and laser-jet photolyses
Journal:   J. Am. Chem. Soc.
Volume:   115
Page(s):   2473 - 2477
Year:   1993
Reference type:   Journal article
Squib:   1993BAN/SCA2473-2477

Reaction:   Methyl, ethoxymethoxyphenyl- → Methylbenzoate + ·C2H5
Reaction order:   1
Reference reaction:   Methyl, ethoxymethoxyphenyl- → Ethyl benzoate + ·CH3
Temperature:   329 K
Rate expression:   2.13x102 [s-1]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

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