Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Andersen, M.RS.; Nilsson, E.JK.; Nielsen, O.J.; Johnson, M.S.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O3
Journal:   J. Photochem. Photobiol. A Chem.
Volume:   199
Page(s):   92 - 97
Year:   2008
Reference type:   Journal article
Squib:   2008AND/NIL92-97

Reaction:   ·Cl + (E)-CF3CH=CHCl → Products
Reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   5.22x10-11 [±7.2x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The rate constant was measured relative to reactions Cl with C2H4 and C2H2.

View full bibliographic record.