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Accessibility information
Author(s):   Butler, E.T.; Mandel, E.; Polanyi, M.
Title:   Rates of pyrolysis and bond energies of substituted organic iodides. Part II
Journal:   Trans. Faraday Soc.
Volume:   41
Page(s):   298 - 306
Year:   1945
Reference type:   Journal article
Squib:   1945BUT/MAN298-306

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1945BUT/MAN298-306   iso-C3H7ICH3CH=CH2 + HI  673 - 765   1.00E13       1.93E05      1
  1945BUT/MAN298-306   CHI3I + ·CHI2  564 - 703   1.00E13       1.55E05      1
  1945BUT/MAN298-306   tert-C4H9Iiso-C4H8 + HI  618 - 718   1.00E13       1.89E05      1
  1945BUT/MAN298-306   CHBr2I → CHBr2 + I  671 - 723   1.00E13       1.73E05      1
  1945BUT/MAN298-306   CHCl2I → CHCl2 + I  673 - 723   1.00E13       1.77E05      1
  1945BUT/MAN298-306   ClCH2CH2ICH2=CHCl + HI  703 - 751   1.00E13       1.92E05      1
  1945BUT/MAN298-306   c-C6H11ICyclohexene + HI  673 - 718   1.00E13       2.06E05      1
  1945BUT/MAN298-306   C6H5-(CH2CH2I)Styrene + HI  703 - 808   1.00E13       2.10E05      1

Search returned 8 records.