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Title: The gas-phase elimination kinetics of 2-hydroxy-2-methylbutyric acid and 2-ethyl-2-hydroxybutyric acid
Journal: Int. J. Chem. Kinet.
Volume: 27
Page(s): 849 - 853
Year: 1995
Reference type: Journal article
Squib: 1995CHU/MAR849-853
Reaction:
C2H5(CH3)C(OH)COOH → C2H5COCH3 + CO + H2O
Reaction order:
1
Temperature:
553 - 593
K
Pressure: 8.96E-2 - 0.32 bar
Rate expression:
7.41x1012 [s-1] e-171278 [±1713 J/mole]/RT
Uncertainty:
1.54999995
Bath gas:
Toluene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 553 | 4.92E-4 |
| 575 | 2.05E-3 |
| 593 | 6.07E-3 |