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Accessibility information
Author(s):   Chuchani, G.; Martin, I.; Rotinov, A.
Title:   The gas-phase elimination kinetics of 2-hydroxy-2-methylbutyric acid and 2-ethyl-2-hydroxybutyric acid
Journal:   Int. J. Chem. Kinet.
Volume:   27
Page(s):   849 - 853
Year:   1995
Reference type:   Journal article
Squib:   1995CHU/MAR849-853

Reaction:   C2H5(CH3)C(OH)COOHC2H5COCH3 + CO + H2O
Reaction order:   1
Temperature:   553 - 593 K
Pressure:  8.96E-2 - 0.32 bar
Rate expression:   7.41x1012 [s-1] e-171278 [±1713 J/mole]/RT
Uncertainty:   1.54999995
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
553 4.92E-4
575 2.05E-3
593 6.07E-3