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Author(s):   Karra, S.B.; Senkan, S.M.
Title:   Analysis of the Chemically Activated CH2Cl/CH2Cl and CH3/CH2Cl Recombination Reactions at Elevated Temperatures Using the Bimolecular Quantum Rice-Ramsperger-Kassel (QRRK) Method
Journal:   Ind. Eng. Chem. Res.
Volume:   27
Page(s):   447 - 451
Year:   1988
Reference type:   Journal article
Squib:   1988KAR/SEN447-451

Reaction:   CH2ClCH2Cl → CH2CH2Cl + ·Cl
Reaction order:   1
Temperature:   500 - 1700 K
Rate expression:   1.26x1016 [s-1] e-338904 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit
Comments:   Fall-off rate constants were presented in table at 0.67, 1.0, 3.0 and 10.0 atm for Ar and CH4 as bath gases.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
500 4.97E-20
600 3.95E-14
700 6.48E-10
800 9.39E-7
900 2.70E-4
1000 2.50E-2
1100 1.02E0
1200 2.23E1
1300 3.04E2
1400 2.86E3
1500 1.99E4
1600 1.09E5
1700 4.87E5