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Author(s):   Ackermann, L.; Hippler, H.; Pagsberg, P.; Reihs, C.; Troe, J.
Title:   Pulse radiolysis, flash photolysis, and shock wave study of the recombination H + benzyl →’ toluene at 300 and 1300-1650 K
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   5247 - 5251
Year:   1990
Reference type:   Journal article
Squib:   1990ACK/HIP5247-5251

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990ACK/HIP5247-5251   Benzene + → 2,4-Cyclohexadien-1-yl  300   2.82E-14              2
  1990ACK/HIP5247-5251   1,4-Dimethylbenzene + → cyclohexadienyl, 3,6-dimethyl-  300   1.83E-13              2
  1990ACK/HIP5247-5251   Toluene + → 6-methyl-cyclohexadienyl  300   1.83E-13              2
  1990ACK/HIP5247-5251   1,3,5-Cycloheptatriene + → cycloheptadienyl radical  300   2.99E-12              2
  1990ACK/HIP5247-5251   Benzyl + Toluene  300 - 1650   4.32E-10              2
  1990ACK/HIP5247-5251   4-Methylbenzyl + 1,4-Dimethylbenzene  300   3.82E-10              2
  1990ACK/HIP5247-5251   Phenyl + Benzene  300   3.65E-10              2

Search returned 7 records.