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Author(s):   Czarnowski, J.
Title:   Formation of glyoxyloxyl chloride, HC(O)C(O)Cl, in the gas-phase oxidation of trichloroethene by NO2
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   1459 - 1462
Year:   1991
Reference type:   Journal article
Squib:   1991CZA1459-1462

Reaction:   C2HCl3 + NO2 → Products
Reaction order:   2
Temperature:   343 - 362 K
Pressure:  2.51E-2 - 0.27 bar
Rate expression:   1.01x10-18 [cm3/molecule s] e-38080 [J/mole]/RT
Bath gas:   NO2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
343 1.61E-24
350 2.10E-24
362 3.25E-24