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Title: Kinetics and mechanism of the thermal gas-phase reaction between NO2 and trichloroethene at 303-362.2 K
Journal: Int. J. Chem. Kinet.
Volume: 24
Page(s): 679 - 687
Year: 1992
Reference type: Journal article
Squib: 1992CZA679-687
Reaction:
C2HCl3 + NO2 → Products
Reaction order:
2
Temperature:
303 - 362
K
Pressure: 1.60E-2 - 0.16 bar
Rate expression:
6.76x10-19 [cm3/molecule s] e-36833 [±8314472 J/mole]/RT
Bath gas:
C2HCl3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 303 | 3.02E-25 |
| 325 | 8.13E-25 |
| 350 | 2.15E-24 |
| 362 | 3.27E-24 |