 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Disproportionation and hydrogen abstraction reactions of trimethylsilyl radicals
Journal: J. Am. Chem. Soc.
Volume: 102
Page(s):
Year: 1980
Reference type: Journal article
Squib: 1980GAM/SAF378
Reaction:
CH3SiD3 + (CH3)3Si· → Other Products + (CH3)3SiD
Reaction order:
2
Reference reaction:
(CH3)3Si· + (CH3)3Si· → (CH3)6Si2
Temperature:
298
K
Pressure: 0.27 bar
Rate expression:
9.48x10-19 [cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Other (direct)
View full bibliographic record.