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Author(s):   Gammie, L.; Safarik, I.; Strausz, O.P.; Roberge, R.; Sandorfy, C.
Title:   Disproportionation and hydrogen abstraction reactions of trimethylsilyl radicals
Journal:   J. Am. Chem. Soc.
Volume:   102
Year:   1980
Reference type:   Journal article
Squib:   1980GAM/SAF378

Reaction:   CH3SiD3 + (CH3)3Si· → Other Products + (CH3)3SiD
Reaction order:   2
Reference reaction:   (CH3)3Si· + (CH3)3Si·(CH3)6Si2
Temperature:   298 K
Pressure:  0.27 bar
Rate expression:   9.48x10-19 [cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

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