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Author(s):   Daugey, N.; Caubet, P.; Bergeat, A.; Costes, M.; Hickson, K.M.
Title:   Reaction kinetics to low temperatures. Dicarbon plus acetylene, methylacetylene, allene and propene from 77 <= T <= 296 K
Journal:   Phys. Chem. Chem. Phys.
Volume:   10
Page(s):   729 - 737
Year:   2008
Reference type:   Journal article
Squib:   2008DAU/CAU729-737

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2008DAU/CAU729-737   C2(X1ΣPlg) + C2H2 → Products  77.00 - 296   4.10E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + C2H2 → Products  77.00   2.30E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + C2H2 → Products  296   1.10E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + CH2=C=CH2 → Products  296   2.70E-10              2
  2008DAU/CAU729-737   C2(X1ΣPlg) + CH2=C=CH2 → Products  77.00 - 296   4.80E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + CH2=C=CH2 → Products  77.00   3.40E-10              2
  2008DAU/CAU729-737   C2(X1ΣPlg) + CH3CCH → Products  77.00 - 296   4.50E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + CH3CCH → Products  77.00 - 296   3.70E-10              2
  2008DAU/CAU729-737   C2(X1ΣPlg) + CH3CH=CH2 → Products  77.00 - 296   4.10E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + CH3CH=CH2 → Products  77.00   3.60E-10              2
  2008DAU/CAU729-737   C2(a3PIu) + CH3CH=CH2 → Products  296   2.30E-10              2
Search returned 11 records.