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Accessibility information
Author(s):   Frerichs, H.; Tappe, M.; Wagner, H.Gg.
Title:   Reactions of fluorobenzene, chlorobenzene and bromobenzene with atomic oxygen (O3P) in the gas phase
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   162
Page(s):   147 - 159
Year:   1989
Reference type:   Journal article
Squib:   1989FRE/TAP147-159

Reaction:   Bromobenzene + → Products
Reaction order:   2
Temperature:   295 - 871 K
Pressure:  2.00E-3 - 6.00E-3 bar
Rate expression:   3.65x10-11 [±1.31x10-11 cm3/molecule s] e-20121 [±2411 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 1.00E-14
300 1.15E-14
350 3.63E-14
400 8.61E-14
450 1.69E-13
500 2.89E-13
550 4.49E-13
600 6.47E-13
650 8.83E-13
700 1.15E-12
750 1.45E-12
800 1.77E-12
850 2.12E-12
871 2.27E-12