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Accessibility information
Author(s):   Bedjanian, Y.; Poulet, G.; Le Bras, G.
Title:   Low-pressure study of the reactions of Br atoms with alkenes. 2. Reactions with ethene and trans-2-butene
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   4026 - 4033
Year:   1999
Reference type:   Journal article
Squib:   1999BED/POU4026-4033

Reaction:   (E)-2-C4H8 + Br·HBr + (E)-CH3CH=CHCH2
Reaction order:   2
Temperature:   233 - 320 K
Pressure:  6.67E-4 - 2.67E-3 bar
Rate expression:   5.8x10-12 [±1.66x10-12 cm3/molecule s] e-7982 [±1355 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
233 9.41E-14
250 1.25E-13
275 1.77E-13
300 2.36E-13
320 2.89E-13