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Author(s):   Chuchani, G.; Martin, I.; Martin, G.
Title:   Neighboring group participation of polar β substituents in the gas-phase pyrolysis of 2-substituted ethyl chlorides
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):   109 - 115
Year:   1979
Reference type:   Journal article
Squib:   1979CHU/MAR109-115

Reaction:   2-Chloroethyl methyl etherCH2=CHOCH3 + HCl
Reaction order:   1
Temperature:   723 - 763 K
Pressure:  7.07E-2 - 0.15 bar
Rate expression:   1.15x1014 [s-1] e-244445 [±7342 J/mole]/RT
Uncertainty:   3.3900001
Bath gas:   2-Chloroethyl methyl ether
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
723 2.52E-4
725 2.81E-4
750 1.09E-3
763 2.12E-3