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Author(s):   Wallington, T.J.; Orlando, J.J.; Tyndall, G.S.
Title:   Atmospheric chemistry of chloroalkanes: intramolecular elimination of HCl from chloromethoxy radicals over the temperature range 264-336 K
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   9437 - 9442
Year:   1995
Reference type:   Journal article
Squib:   1995WAL/ORL9437-9442

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995WAL/ORL9437-9442   O2 + CH2ClO → HC(O)Cl + HO2  264 - 336   5.60E-23       -2.74E04   3.61E-18  2
  Reference reaction:  CH2ClO → HCO + HCl 1

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