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Title: Chlorine atom initiated reactions of selected tropospheric halocarbons - Kinetic and product studies
Journal: Can. J. Chem.
Volume: 84
Page(s): 1686 - 1695
Year: 2006
Reference type: Journal article
Squib: 2006GAR/TIM1686-1695
Reaction:
C2HCl3 + ·Cl → Products
Reaction order:
2
Reference reaction:
C2H4 + ·Cl → Products
Temperature:
298 - 358
K
Pressure: 1.01 bar
Rate expression:
4.6x10-12 [±1.3x10-12 cm3/molecule s] e-7034 [±690 J/mole]/RT
Category: Experiment
Data type:
Relative value normalized by a reference value
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In both real time and by end product analysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 2.69E-13 |
| 300 | 2.74E-13 |
| 325 | 3.41E-13 |
| 350 | 4.10E-13 |
| 358 | 4.33E-13 |