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Author(s):   Garib, A.;Timerghazin, O.K.;Ariya, P.A.
Title:   Chlorine atom initiated reactions of selected tropospheric halocarbons - Kinetic and product studies
Journal:   Can. J. Chem.
Volume:   84
Page(s):   1686 - 1695
Year:   2006
Reference type:   Journal article
Squib:   2006GAR/TIM1686-1695

Reaction:   C2HCl3 + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H4 + ·Cl → Products
Temperature:   298 - 358 K
Pressure:  1.01 bar
Rate expression:   4.6x10-12 [±1.3x10-12 cm3/molecule s] e-7034 [±690 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In both real time and by end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.69E-13
300 2.74E-13
325 3.41E-13
350 4.10E-13
358 4.33E-13