Author(s):   Demissy, M.; Lesclaux, R.
Title:   Kinetics of Hydrogen Abstraction by NH₂ Radicals from Alkanes in the Gas Phase. A Flash Photolysis-Laser Resonance Absorption Study
Journal:   J. Am. Chem. Soc.
Volume:   102
Page(s):
Year:   1980
Reference type:   Journal article
Squib:   1980DEM/LES2897

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1980DEM/LES2897	CH₄ + ·NH₂ → ·CH₃ + NH₃	300 - 520	8.30E-13	4.39E04	2
1980DEM/LES2897	C₂H₆ + ·NH₂ → ·C₂H₅ + NH₃	300 - 520	6.14E-13	2.99E04	2
1980DEM/LES2897	C₃H₈ + ·NH₂ → Other Products + NH₃	300 - 520	7.47E-13	2.58E04	2
1980DEM/LES2897	iso-C₄H₁₀ + ·NH₂ → Products	300 - 520	3.82E-13	2.05E04	2
1980DEM/LES2897	1-C₄H₁₀ + ·NH₂ → Other Products + NH₃	300 - 520	1.16E-12	2.55E04	2
1980DEM/LES2897	H₂ + ·NH₂ → NH₃ + H·	300 - 520	2.09E-12	3.56E04	2

Search returned 6 records.