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Author(s):   Niki, H.; Maker, P.D.; Savage, C.M.; Breitenbach, L.P.
Title:   FTIR studies of the kinetics and mechanism for the reaction of Cl atom with formylchloride
Journal:   Int. J. Chem. Kinet.
Volume:   12
Year:   1980
Reference type:   Journal article
Squib:   1980NIK/MAK915

Reaction:   HC(O)Cl + ·ClClCO + HCl
Reaction order:   2
Reference reaction:   CH3Cl + ·Cl·CH2Cl + HCl
Temperature:   700 K
Pressure:  0.93 bar
Rate expression:   7.8x10-13 [cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

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