Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Taylor, R.
Title:   Measurement of electrophilic aromatic reactivities via pyrolysis of 1-arylethyl acetates. Part II. The 2- and 3-positions of furan and thiophen
Journal:   J. Chem. Soc. B
Year:   1968
Reference type:   Journal article
Squib:   1968TAY1397

Reaction:   2-Thiophenemethanol, α-methyl-, acetate → CH3C(O)OH + Thiophene, 2-ethenyl-
Reaction order:   1
Temperature:   591 - 642 K
Rate expression:   2.09x1012 [s-1] e-172110 [J/mole]/RT
Bath gas:   2-Thiophenemethanol, α-methyl-, acetate
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
591 1.28E-3
600 2.17E-3
625 8.64E-3
642 2.08E-2