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Title: Measurement of electrophilic aromatic reactivities via pyrolysis of 1-arylethyl acetates. Part II. The 2- and 3-positions of furan and thiophen
Journal: J. Chem. Soc. B
Page(s):
Year: 1968
Reference type: Journal article
Squib: 1968TAY1397
Reaction:
2-Thiophenemethanol, α-methyl-, acetate → CH3C(O)OH + Thiophene, 2-ethenyl-
Reaction order:
1
Temperature:
591 - 642
K
Rate expression:
2.09x1012 [s-1] e-172110 [J/mole]/RT
Bath gas:
2-Thiophenemethanol, α-methyl-, acetate
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 591 | 1.28E-3 |
| 600 | 2.17E-3 |
| 625 | 8.64E-3 |
| 642 | 2.08E-2 |